This week's book giveaway is in the General Computing forum. We're giving away four copies of Arduino in Action and have Martin Evans, Joshua Noble, and Jordan Hochenbaum on-line! See this thread for details.
I believe, you can do it very easily. I have done these things in past using other cards such as payflex. But i guess it has only basic security. You can refer java card API docs and write an application on PC (using java or VC++). you will need card reader attached to PC. Your PC application can send a command to a card and then card responds.