Frankly speaking, this book is not for a biginer in Java/J2EE programming. But to answer your query:
Will this book will help me to start knowing about web services from basic..
As you can see from the service-oriented-java-business-integration-Table-of-Contents.pdf, this book doesn't require any previous knowledge on JBI and/or ESB. Pre-knowledge of web services is desirable, but if you don't have any experience in web services, still the book has got enough manuscript and samples which will teach you quickly on Web Services and related technologies so that you can continue reading (and understand too) the rest of the book.