The ultimate reference for this is the JVM specification. The major and minor version numbers are bytes 7/8 and 5/6 of the class file, respectively. This page explains it with a bit more detail. A library like Javassist provides an easily usable API for getting at this information (as do others like ASM and BCEL).
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Of course the classfile version number will not tell you the actual compiler used (say Sun or IBM), just the classfile format that was generated by that compiler (which is all you should have to worry about anyway, unless you suspect there's a bug in that generated bytecode in which case you should contact the person who compiled it and tell them). [ November 28, 2006: Message edited by: Jeroen T Wenting ]