This week's book giveaway is in the OCAJP 8 forum. We're giving away four copies of OCA Java SE 8 Programmer I Study Guide and have Edward Finegan & Robert Liguori on-line! See this thread for details.
I see you placed JBoss AS into Program Files. Bad move. Spaces in path names can cause problems with various Java libraries. I suggest you place JBoss AS elsewhere (I have mine at d:\opt\jboss\jboss-5.0.1.GA).
You should also try starting JBoss AS from the command line. Once that is running properly we can tackle getting it to run in Eclipse.