As Ian pointed out, 6.5 can be represented
exactly in binary, whereas 3.2 can't. That's why the difference in precision doesn't matter for 6.5, so 6.5 == 6.5f.
To quickly refresh how binary numbers work:
100 -> 4
10 -> 2
1 -> 1
0.1 -> 0.5 (or 1/2)
0.01 -> 0.25 (or 1/4)
etc.
6.5 in binary: 110.1 (exact result, the rest of the digits are just zeroes)
3.2 in binary: 11.001100110011001100110011001100110011001100110011001101... (here precision matters!)
A float only has 24 bits precision (the rest is used for sign and exponent), so:
3.2f in binary: 11.0011001100110011001100 (not equal to the double precision approximation)
There's a handy calculator for things like this at
http://www.digitconvert.com/
Basically it's the same as when you're writing 1/5 and 1/7 in decimal numbers:
1/5 = 0,2
1,7 = 0,14285714285714285714285714285714...