Here is a link that gives you a quick difference.
http://www.ibm.com/developerworks/library/ws-tip-jaxwsrpc.html I went through it a while back. I have not worked extensively with web services but I guess you could expect questions on
SOAP; what terms like UDDI, WSDL, mean; what role XML plays; what APIs are available for web service communication with or without attachments; security; XML basics; what support application servers provide to develop web services; how a
servlet or
ejb can be turned into a web service.
That would pretty much be my exposure. I ll let some one with more experience to add to this list, since I have never designed a full fledged web service. Good luck