Hi!
Theoretically you can use (almost) any transport type for web services, like email, JMS, FTP, HTTP or pidgeon, but I think that HTTP is the only one officially supported at the moment.
If you look at the JAX-WS web page
https://jax-ws.dev.java.net/ there is a link to JAX-WS over JMS.
The best place to look for information is the JAX-WS standards document:
http://jcp.org/en/jsr/detail?id=224
Best wishes!