Hi!
Yes, you can access your web service if you are using JavaSE 6, which has all the necessary classes built in.
If you are using earlier versions of JavaSE, then you can still access the web service but have to include additional libraries.
The Metro web service stack also includes client libraries. It can be found here:
https://metro.dev.java.net/
Use the wsimport command included in the JDK to generate client artifacts (classes etc) from the WSDL of the .NET web service.
Here is a tutorial showing how to develop SOAP web service clients in NetBeans:
http://netbeans.org/kb/docs/websvc/client.html
If you need additional help, please do not hesitate to post again!
Best wishes!