This is generally not possible.
I, for example, have completely turned autorun off on my computer, since I really don't want anybody to run a program when I insert a DVD or stick in a USB. I usually can figure out myself what to click, thanks.
There may be a group of users who actively want to have a program run automatically when they stick a USB in. However, they are probably a minority. You need to provide means for the rest of users, who do not want to allow this, to use your application in a different way.