I don't know the Spring MVC mocking framework, but any mocking framework requires you to provide (if needed) a return value when a method on a mocked object is called.
You say you have an NPE occurring. I assume this is the List (Emp_All), if not then you'll have to provide some more info as to what is null.
If I'm correct, then Emp_All is null because it looks to me as if you haven't provided any return value via the mocked employRepository.
Looking at this
SO thread it looks like you need to have a mocked version of your employRepository accessible.
Then you can set up some expectations (when(employRepo.findAll()).thenReturn(your list of employees)).