There is a free download PDF of "Spring Into Action 2.0" and then there is the online documentation and references. Next there are a lot of sample spring downloads to start from......Google spring examples......This is the best one I found..
Spring examples. It is a huge task to know all of spring. My recommendation is to have a basic design you are interested in , and start building a framework based on that. As you work with what you're building you'll get a great understanding of it. Add functionality as required. As you keep changing the design you'll be configuring spring like a pro once you work with it for a while. Because you can configure spring in many ways and the number of design choices are almost unlimited, it's unlikely you'll need to know every single aspect because it will not be necessary.
Good Luck.
Cheers,
Greg Funston